Professor Cameron Kepert

BSc UWA; PhD RIGB/Lond
ARC Future Fellow
Professor of Chemistry

F11 - Chemistry Building
The University of Sydney

Telephone 61 2 9351 5741
Fax 61 2 9351 3329

Website CO2MOF Network Group
Contact Details
The Kepert Group

Biographical details

  • BSc (Hons. I), University of Western Australia
  • PhD, Royal Institution of Great Britain/University of London
  • Junior Research Fellow (Christ Church), University of Oxford
  • Appointed at the University of Sydney, 1999
  • ARC Federation Fellowship, 2005
  • Liversidge Lectureship, RSNSW, 2008
  • Australasian Lectureship, RSC, 2009

Research interests

  • Materials chemistry
  • Molecular framework materials
  • X-ray diffraction
  • Nanoporosity
  • Electronic and magnetic properties of solids
  • Phase transitions (structural, electronic and magnetic)

Coordination Framework Materials: Coordination frameworks are crystalline solids that contain extended networks constructed by the linkage of metal atoms by multiply-coordinating polydentate ligands. A rapid growth in the study of these materials has arisen from the realisation that metal-organic framework synthesis offers considerable flexibility and control over structure and properties, thereby offering rare pathways to rational materials design. This flexibility originates from the enormous structural and chemical diversities afforded by molecular systems, features that are less prevalent in many other branches of materials chemistry.

The recent emergence of nanoporosity in molecular frameworks has led to widespread speculation that such materials may be ideally suited for applications such as molecular separation, sensing and heterogeneous catalysis. Our primary research efforts are being directed towards exploring these issues, addressing, in particular, whether there are any limitations to this porosity and to what extent the frameworks may be thought of as rigid. Experimentation involves the synthesis of new materials by diffusion-controlled and solvothermal methods, and structural and physical characterisations using techniques that include single crystal and powder X-ray diffraction, vibrational spectroscopy (IR and Raman), TGA/DSC of guest desorption and sorption, NMR, SQUID magnetometry, EPR and theoretical modelling of guest molecule docking and packing.

Chiral Phases: The search for chiral nanoporous materials, widely regarded as a Holy Grail within solid state chemistry, is driven by the potential application of such materials for chiral separations and enantioselective syntheses. We have recently made significant in-roads into this area by developing a large and diverse array of porous, chiral molecular framework solids, including some that are the only such materials known that can be synthesised homochirally. Experiments show that these materials display a high degree of selectivity to molecular guest-exchange, as well as retaining structural framework integrity with guest removal. Investigations into the direct application of these phases for enantioseparation are underway, with an aim towards designing systems for the separation of small drug-precursor molecules

In-situ Structural Investigations: We have recently performed unique in-situ single crystal X-ray diffraction experiments of guest desorption and sorption to demonstrate the nanoporosity of specific molecular framework materials. These studies are noteworthy in providing the first quantitative proof that desolvated phases of both co-ordination and hydrogen-bonded framework lattices may be robust enough to support large regions of complete void, thereby drawing a direct link with more conventional nanoporous materials such as zeolites. Such studies are being combined with in-situ techniques such as DSC/TGA, vibrational spectroscopy, NMR and molecular modelling to generate an overall picture that combines structural information with an understanding of the selectivity, dynamics and energetics of guest-exchange.

Electronic and Magnetic Properties: The incorporation of atomic or molecular constituents with electronic or magnetic function (e.g., localised electrons, delocalised pI-systems, redox-active species, etc.) into molecular frameworks is being investigated with an aim towards constructing materials with novel electronic and magnetic properties. The vast control over structure and chemical functionality that is afforded by this molecular approach allows the property-directed design and synthesis of new magnetic and electronic materials, including, importantly, the possible combination of these properties with nanoporosity.

Hydrogen Storage: The safe and efficient storage of hydrogen gas represents one of the central challenges on the road to the proposed Hydrogen Economy. Nanoporous coordination framework materials have recently been shown to sorb large volumes of hydrogen gas at low temperature and high pressure, a property that may be attributed to their very high surface areas. Two principal challenges exist to optimise the extent and conditions of loading: 1) maximisation of surface area per mass and volume, thereby maximising potential uptake, and 2) maximisation of the dihydrogen physisorption interaction energy, thereby favouring loading at higher temperatures and lower pressures. Our investigations in this area have uncovered very high hydrogen uptakes in Prussian Blue materials and a range of highly porous metal-organic frameworks.

Negatve Thermal Expansion: We have recently discovered that a broad family of coordination frameworks undergo negative thermal expansion (NTE, ie. contraction upon warming) over broad temperature ranges. We attribute this highly unusual and potentially useful property to the existence of low energy transverse vibrations of molecular bridges within the open framework structures, the amplitude of which increase with increasing temperature. Through tuning the energy of these vibrational modes we have achieved both unprecedented NTE and approximate zero thermal expansion (ZTE) behaviour.

Awards and honours

  • Rennie Medal, RACI, 2003
  • Le Fèvre Prize, Australian Academy of Science, 2004
  • Edgeworth David Medal, Royal Society of NSW, 2004
  • Malcolm McIntosh Prize for Physical Scientist of the Year, 2005
  • Alan Sargeson Award, RACI, 2006

Selected grants

2015

  • Advanced Dynamic Function in Metal-Organic Framework Materials; Kepert C; Australian Research Council (ARC)/Discovery Projects (DP).

2014

  • Multifunctional hybrid spin crossover materials; Kepert C, Letard J, Neville S, Murray K; Australian Research Council (ARC)/Discovery Projects (DP).

2013

  • Exploiting the Kubas Interaction in the Synthesis of Advanced Carbon Nanostructures for Hydrogen Storage; Choucair M, Kepert C; DVC Research/Postdoctoral Research Fellowship Scheme.
  • Thermogravimetric Analyser (TGA); Kepert C, D'Alessandro D, Perrier S, Hawkett B, Hibbs D, Wheate N, Harris A, Minett A, Ling C, Kennedy B; DVC Research/Equipment Grant.
  • Perpetual account for Cameron Kepert - Selective gas-separation for energy applications using Metal-Organic Frameworks; Kepert C, Ogilvie S; Australian Institute of Nuclear Science and Engineering (AINSE)/Access to Facilities and/or Services.

2012

  • A State-of-the-art Magnetic Property Measurement Facility for the Development of Advanced Materials and Biomedical Technologies in the Sydney Basin; Li S, Amal R, Kepert C, Zhang C, Sheppard L, Zheng R, Kennedy B, Sahajwalla V, Guo Z, Ling C, D'Alessandro D, Klose F, Jiang X; Australian Research Council (ARC)/Linkage Infrastructure, Equipment and Facilities (LIEF).
  • Perpetual account for travel grants for Dr Natasha Sciortino; Sciortino N, Kepert C, Das A; Australian Synchrotron Company Limited/International Access Program.
  • Advanced Functional Properties in Metal-Organic Frameworks; Kepert C, D'Alessandro D; Australian Research Council (ARC)/Discovery Projects (DP).

2011

  • Noivice user access to facilities: Powder neutron diffraction studies of in situ gas adsorption in the new metal-organic framework Zr(BDC); Kepert C, Chen C; Australian Institute of Nuclear Science and Engineering (AINSE)/Access to Facilities and/or Services.
  • Solving the Energy Waste Roadblock (SIEF Grant); Kepert C, D'Alessandro D; Science and Industry Endowment Fund/Research Support.
  • Determining vacancy ordering through pair distribution function analysis; Cameron L, Kepert C; Australian Synchrotron Company Limited/International Access Program.
  • Innovative Synchrotron Science - Access Program to the Australian National Beamline Facility and Cutting-Edge Beamlines at International Synchrotrons; Lay P, Waite T, Gerson, A, Harris H, Collins R, Dillon C, Brugger J, Garrett R, Wilce M, De Marco R, Tardio J, Spiccia L, Zhang L, Aguilar M, Hambley T, Harmer-Bassell S, Burton E, Bush R, Johnston S, Trevitt A, Kepert C, Chantler C, Shimomura O, Bond C, Gray E, Noller B, Gentle I, Sullivan L, Creagh D, Low I; Australian Research Council (ARC)/Linkage Infrastructure, Equipment and Facilities (LIEF).
  • Tailored Thermal Exoansion in Framework Materials; Kepert C, Wu Y, Price J, Diwa A; Australian Synchrotron Company Limited/Funding Application for Interstate User Groups.

2010

  • Spin Switching in Nanoporous, Nanomolecular and Multifunctional Hybrid Systems; Kepert C, Murray K, Letard J, Steel P; Australian Research Council (ARC)/Discovery Projects (DP).
  • Redox- and Photo- Active Metal-Organic Frameworks: Physical properties and application in gas separations; D'Alessandro D, Kepert C; DVC Research/Postdoctoral Research Fellowship Scheme.
  • Federated Single Crystal X-ray Structural Analysis Facility; Kepert C, Guss M, Malby R, Jormakka M, Cole M, Dixon N, Kearley G; Australian Research Council (ARC)/Linkage Infrastructure, Equipment and Facilities (LIEF).
  • High performance analytical tools to strengthen clean energy research; Amal R, Kepert C; Australian Research Council (ARC)/Linkage Infrastructure, Equipment and Facilities (LIEF).
  • Functional Molecular Nanomaterials for Next-Generation Technologies; Kepert C; Australian Research Council (ARC)/Future Fellowships (FT).

2009

  • Hydrogen Storage and Negative Thermal Expansion Properties of Novel Cyanide-Bridged Coordination Frameworks; Kepert C, Chadbourne J; Australian Institute of Nuclear Science and Engineering (AINSE)/Scholarship.
  • A High-Throughput Neutron Spectrometer for The Study of Atomic and Molecular Motion at ANSTO; Mather D, Kepert C; Australian Research Council (ARC)/Linkage Infrastructure, Equipment and Facilities (LIEF).
  • Advanced Functional Properties in Coordination Framework Materials; Kepert C; Australian Research Council (ARC)/Discovery Projects (DP).

2008

  • Guest effects on Spin Crossover Nanoporous Molecular Frameworks - AINSE Post Graduate Research Award (PGRA); Kepert C, Fellows E; Australian Institute of Nuclear Science and Engineering (AINSE)/Scholarship.
  • Negative Thermal Expansion in Metal Cyanide Coordination Framework Materials; Kepert C, Duyker S; Australian Institute of Nuclear Science and Engineering (AINSE)/Awards.
  • Energy storage in nanoporous metal-organic framework materials; Kepert C; American Chemical Society/Petroleum Research Fund.
  • Comprehensive Analysis Facility for Thin Films and Surfaces; Bilek M, Ling C, Munroe P, Stevens-Kalceff M, Riley D, Holland A, Williams J, McKenzie D, Kennedy B, Hoffman M, Valanoor N, McCulloch D, Green M, Kepert C, Kalantar-Zadeh K, Maschmeyer T, Conibeer G, Gross K, Burford R, Mitchell A, Austin M, Samarin S; Australian Research Council (ARC)/Linkage Infrastructure, Equipment and Facilities (LIEF).
  • Negative Thermal Expansion in Cu3(btc)2; Wu Y, Kepert C; Australian Institute of Nuclear Science and Engineering (AINSE)/Awards.
  • Comprehensive Analysis Facility for Thin Films and Surfaces; Mitchell A, Stevens-Kalceff M, Kepert C, Kalantar-Zadeh K, Conibeer G, Gross K, Burford R, Samarin S, McKenzie D, Valanoor N, McCulloch D, Ling C, Maschmeyer T, Munroe P, Riley T, Holland A, Williams J, Kennedy B, Hoffman M, Bilek M, Green M; Australian Research Council (ARC)/Linkage Infrastructure, Equipment and Facilities (LIEF).

2007

  • Physical Property Measurement System for Materials Characterisation; Kepert C, Maschmeyer T, Kennedy B, Ling C, Schmid S, Ekins-Daukes N, Robinson R, Stride J, Mai Y; Australian Research Council (ARC)/Linkage Infrastructure, Equipment and Facilities (LIEF).
  • Hydrogen storage in nanoporous coordination framework materials; Kepert C; DVC Research/Sustainable Energy Research Grant (SERG).

2006

  • Polynuclear Spin-Crossover Molecular Switches: Host-Guest Chemistry, Magnetism And Memory; Kepert C; Australian Research Council (ARC)/Linkage International: ARC International Fellowships (ARCIF).
  • Molecular Framework Materials: Nanoporosity and anomalous thermal expansion; Kepert C; Australian Research Council (ARC)/Discovery Projects (DP).
  • Guest-Dependent Spin Crossover In Molecular Framework Materials - Aps, Usa, 22-28 March 2006; Halder G, Kepert C; Australian Nuclear Science and Technology Organisation/Australian Synchrotron Research Program.
  • e-Research Infrastructure for the Molecular and Materials Structure Sciences; Turner P, Martin J, Guss M, Kepert C; Australian Research Council (ARC)/Linkage Infrastructure, Equipment and Facilities (LIEF).

2005

  • Light Unduced Electronic Switching In Nanoporous Materials And Supramolecular Clusters; Kepert C, Guionneau P, Murray K; DEST/Innovation Access Programme-International Science&Technology Grants.
  • 2444 - Evidence For H2 Sorption By A Nanoporous Coordination Polymer By In-Situ Single Crystal Neutron Diffraction; Kepert C; Australian Institute of Nuclear Science and Engineering (AINSE)/Awards.
  • Advanced Molecular Nanomaterials; Kepert C; Australian Research Council (ARC)/Federation Fellowship (FF).
  • Scientific Instruments as ICT Components in Building a GrEMLIN for e-Research; Kepert C, Turner P, Zomaya A, Abramson D, Chiu K, Hauser N, Hursthouse M, McMullen D, Pailthorpe B; Australian Research Council (ARC)/Special Research Initiatives (SRI).
  • Anomalous Thermal Expansion Materials; Kepert C; University of Sydney/Research & Development.
  • Polynuclear spin-crossover molecular switches: host-guest chemistry, magnetism and memory; Murray K, Toftlund-Neilsen H, Kepert C, Murray K, Toftlund H, Steel P; Australian Research Council (ARC)/Discovery Projects (DP).

2004

  • Molecular and Materials Structure Network; Turner P, Kepert C, Collins M, Hambley T, Hanrahan J, Kennedy B, Lay P; Australian Research Council (ARC)/Research Networks (ARCRN).
  • Anomalous thermal expansion materials; Kepert C; DVC Research/Research and Development Scheme: Research and Development (R&D).
  • Australian Synchrotron Research Program Research Internship - Ms Karena Chapman; Kepert C; Australian Nuclear Science and Technology Organisation/Australian Synchrotron Research Program.
  • Synthesise upwards of ten crystals of three different anomalous expansion piezoelectric materials by two different methods; Kepert C, James L; Ucom Ten Pty Ltd/Controlled Entity.

2003

  • A grid enabled network for the molecular and materials structure sciences; Kepert C; Australian Research Council (ARC)/Special Research Initiatives (SRI).
  • Nanoporous Molecular Frameworks: Chirality Host-Guest Chemistry and Nanoscale Templation; Kepert C, Stampfl A; Australian Research Council (ARC)/Discovery Projects (DP).
  • Not known; Kepert C; DVC Research/Research and Development Scheme: Research and Development (R&D).
  • Ultra-Sensitive CCD Diffractometer with High Intensity X-ray Photon Generator; Hambley T, Kepert C, Turner P, Spackman M, Williams P, Pyne S, Try A, Hibbs D; Australian Research Council (ARC)/Linkage Infrastructure, Equipment and Facilities (LIEF).
  • Generic Account Code for travel under the Access to Major Research Facilities Program _ Dr C Kepert; Kepert C; Australian Nuclear Science and Technology Organisation/Major Research Facilities Program.

2002

  • Cooperativity in Spin-Crossover Systems: Memory, Magnetism and Microporosity; Kepert C, Murray P; Australian Research Council (ARC)/Discovery Projects (DP).
  • Generic Account Code for travel under ANSTO Australian Synchrotron Research Program_Dr C Kepert; Kepert C; Australian Synchrotron Research Program (ASRP)/Research Grant.
  • Porous Mineral Formulations for Controlled-Release Applications; Kepert C, Thomson S, Matthews O, Anderson T; Australian Research Council (ARC)/Linkage Projects (LP).

2001

  • Linkage 2002 - Porous Mineral Formulations for Controlled-Release Applications LP0209078; Kepert C, Quartararo N; Crop Care Australasia Pty Ltd/Project Support.
  • Advanced materials: New phases for chiral separations; Kepert C; DVC Research/Research and Development Scheme: Research and Development (R&D).
  • Microporous Spin-Switching Materials; Kepert C; Australian Research Council (ARC)/Large Research Grants (LRG).

2000

  • New approaches to chiral microporous materials.; Kepert C; Australian Research Council (ARC)/Small Grants.
  • Porous mineral formulations for controlled release applications: agreement between Crop Care Australasia and The University of Sydney.; Anderson P, Kepert C; Crop Care Australasia Pty Ltd/BLO Project.
  • Microporous molecular frameworks: chirality and guest-exchange; Kepert C, Halder G; Australian Research Council (ARC)/Large Research Grants (LRG).
  • Spin-crossover materials: metastability and microporosity.; Kepert C; University of Sydney/University Research Grant.

Selected publications

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Book Chapters

  • Kepert, C. (2011). Metal-organic framework materials. In Duncan W. Bruce; Dermot OHare; Richard I. Walton (Eds.), Porous Materials, (pp. 1-67). United Kingdom: John Wiley & Sons.
  • Murray, K., Kepert, C. (2004). Cooperativity In Spin Crossover Systems: Memory, Magnetism And Microporosity. In Philipp Gutlich & Harold A. Goodwin (Eds.), Topics in Current Chemistry: Volume 233 - Spin Crossover in Transition Metal Compounds I, (pp. 195-228). Berlin: Springer.

Journals

  • Sciortino, N., Neville, S., Desplanches, C., Letard, J., Martinez, V., Real, J., Moubaraki, B., Murray, K., Kepert, C. (2014). An investigation of photo- and pressure-induced effects in a pair of isostructural two-dimensional spin-crossover framework materials. Chemistry: A European Journal, 20(24), 7448-7457. [More Information]
  • Yuan, A., Zhou, H., Diao, G., Southon, P., Kepert, C., Liu, L. (2014). Gas and vapor adsorption in octacyanometallate-based frameworks Mn2[M(CN)8] (M = W, Mo) with exposed Mn2+ sites. International Journal of Hydrogen Energy, 39(2), 884-889. [More Information]
  • Peterson, V., Southon, P., Halder, G., Price, D., Bevitt, J., Kepert, C. (2014). Guest Adsorption in the Nanoporous Metal-Organic Framework Cu3(1,3,5-Benzenetricarboxylate)2: Combined In Situ X-ray Diffraction and Vapor Sorption. Chemistry of Materials, 26(16), 4712-4723. [More Information]
  • Faust, T., Usov, P., D'Alessandro, D., Kepert, C. (2014). Highly unusual interpenetration isomers of electroactive nickel bis(dithiolene) coordination frameworks. Chemical Communications, 50(84), 12772-12774. [More Information]
  • Ogilvie, S., Duyker, S., Southon, P., Peterson, V., Kepert, C. (2014). Host-guest adsorption behavior of deuterated methane and molecular oxygen in a porous rare-earth metal-organic framework. Powder Diffraction, 128(11), 1-6. [More Information]
  • Wu, Y., Peterson, V., Luks, E., Darwish, T., Kepert, C. (2014). Interpenetration as a mechanism for negative thermal expansion in the metal-organic framework Cu3(btb)2 (MOF-14). Angewandte Chemie (International Edition), 53(20), 5175-5178. [More Information]
  • Murphy, M., Keene, T., Price, J., D'Alessandro, D., Kepert, C. (2014). Magnetic and electronic properties of three new hetero-bimetallic coordination frameworks [Ru2(02CR)4][Au(CN)2] (R = benzoic acid, Furan-2-carboxylate, or Thiophen-2-carboxylate). Australian Journal of Chemistry: an international journal for chemical science, 67(11), 1607-1611. [More Information]
  • Murphy, M., Usov, P., Rizzuto, F., Kepert, C., D'Alessandro, D. (2014). Magnetic, electrochemical and optical properties of a sulfate-bridged Co(II) imidazole dimer. New Journal of Chemistry, 38(12), 5856-5860. [More Information]
  • Keene, T., Murphy, M., Price, J., Sciortino, N., Southon, P., Kepert, C. (2014). Multifunctional MOFs through CO2 fixation: a metamagnetic kagome lattice with uniaxial zero thermal expansion and reversible guest sorption. Dalton Transactions, 43(39), 14766-14771. [More Information]
  • Sundberg, J., Cameron, L., Southon, P., Kepert, C., McKenzie, C. (2014). Oxygen chemisorption/desorption in a reversible single-crystal-to-single-crystal transformation. Chemical Science, 5(10), 4017-4025. [More Information]
  • Clements, J., Price, J., Neville, S., Kepert, C. (2014). Perturbation of Spin Crossover Behavior by Covalent Post-Synthetic Modification of a Porous Metal-Organic Framework. Angewandte Chemie (International Edition), 53(38), 10164-10168. [More Information]
  • Cowan, M., Miller, R., Southon, P., Price, J., Yazaydin, O., Lane, J., Kepert, C., Brooker, S. (2014). Selective gas adsorption in a pair of robust isostructural MOFs differing in framework charge and anion loading. Inorganic Chemistry, 53(22), 12076-12083. [More Information]
  • Reichel, F., Clegg, J., Gloe, K., Gloe, K., Weigand, J., Reynolds, J., Li, C., Aldrich-Wright, J., Kepert, C., Lindoy, L., et al (2014). Self-assembly of an imidazolate-bridged Fe(III)/Cu(II) heterometallic cage. Inorganic Chemistry, 53(2), 688-690. [More Information]
  • Li, F., Sciortino, N., Clegg, J., Neville, S., Kepert, C. (2014). Self-assembly of an octanuclear high-spin FeII molecular cage. Australian Journal of Chemistry: an international journal for chemical science, 67(11), 1625-1628. [More Information]
  • Klein, M., Sciortino, N., Ragon, F., Housecroft, C., Kepert, C., Neville, S. (2014). Spin crossover intermediate plateau stabilization in a flexible 2-D Hofmann-type coordination polymer. Chemical Communications, 50(29), 3838-3840. [More Information]
  • Pages, B., Li, F., Wormell, P., Ang, D., Clegg, J., Kepert, C., Spare, L., Danchaiwijit, S., Aldrich-Wright, J. (2014). Synthesis and analysis of the anticancer activity of platinum(II) complexes incorporating dipyridoquinoxaline variants. Dalton Transactions, 43(41), 15566-15575. [More Information]
  • Ragon, F., Yaksi, K., Sciortino, N., Chastanet, G., Letard, J., D'Alessandro, D., Kepert, C., Neville, S. (2014). Thermal spin crossover behaviour of two-dimensional Hofmann-type coordination polymers incorporating photoactive ligands. Australian Journal of Chemistry: an international journal for chemical science, 67(11), 1563-1573. [More Information]
  • Sciortino, N., Neville, S., Letard, J., Moubaraki, B., Murray, K., Kepert, C. (2014). Thermal- and light-induced spin-crossover bistability in a disrupted Hofmann-type 3D framework. Inorganic Chemistry, 53(15), 7886-7893. [More Information]
  • Duyker, S., Halder, G., Southon, P., Price, D., Edwards, A., Peterson, V., Kepert, C. (2014). Topotactic structural conversion and hydration-dependent thermal expansion in robust LnMIII(CN)6 ·nH2O and flexible ALnFeII(CN)6·nH2O frameworks (A = Li, Na, K; Ln = La-Lu, Y; M = Co, Fe; 0 ≤ n ≥ 5). Chemical Science, 5(9), 3409-3417. [More Information]
  • Neville, S., Halder, G., Murray, K., Moubaraki, B., Kepert, C. (2013). A family of three-dimensional molecular framework materials containing the three-connecting ligands 2,4,6-tris(n'-pyridyl)-1,3,5-triazine: 3-tpt and 4-tpt. Australian Journal of Chemistry: an international journal for chemical science, 66(4), 452-463. [More Information]
  • Murphy, M., D'Alessandro, D., Kepert, C. (2013). A porous Mn(v) coordination framework with PtS topology: assessment of the influence of a terminal nitride on CO(2) sorption. Dalton Transactions, 42(37), 13308-13310. [More Information]
  • Das, A., Choucair, M., Southon, P., Mason, J., Zhao, M., Kepert, C., Harris, A., D'Alessandro, D. (2013). Application of the piperazine-grafted CuBTTri metal-organic framework in postcombustion carbon dioxide capture. Microporous and Mesoporous Materials, 174(2013), 74-80. [More Information]
  • Lyndon, R., Konstas, K., Ladewig, B., Southon, P., Kepert, C., Hill, M. (2013). Dynamic Photo-Switching in Metal–Organic Frameworks as a Route to Low-Energy Carbon Dioxide Capture and Release. Angewandte Chemie (International Edition), 52(13), 3695-3698. [More Information]
  • Lock, N., Christensen, M., Kepert, C., Iversen, B. (2013). Effect of gas pressure on negative thermal expansion in MOF-5. Chemical Communications, 49(8), 789-791. [More Information]
  • Leong, C., Faust, T., Turner, P., Usov, P., Kepert, C., Babarao, R., Thornton, A., D'Alessandro, D. (2013). Enhancing selective CO(2) adsorption via chemical reduction of a redox-active metal-organic framework. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 42(27), 9831-9839. [More Information]
  • Ogilvie, S., Duyker, S., Southon, P., Peterson, V., Kepert, C. (2013). Identification of bridged CO(2) binding in a Prussian blue analogue using neutron powder diffraction. Chemical Communications, 49(82), 9404-9406. [More Information]
  • Duyker, S., Peterson, V., Kearley, G., Ramirez-Cuesta, A., Kepert, C. (2013). Negative thermal expansion in LnCo(CN)6 (Ln=La, Pr, Sm, Ho, Lu, Y): Mechanisms and compositional trends. Angewandte Chemie (International Edition), 52(20), 5266-5270. [More Information]
  • Lock, N., Christensen, M., Wu, Y., Peterson, V., Thomsen, M., Piltz, R., Ramirez-Cuesta, A., McIntyre, G., Norén, K., Kutteh, R., Kepert, C., et al (2013). Scrutinizing negative thermal expansion in MOF-5 by scattering techniques and ab initio calculations. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 42(6), 1996-2007. [More Information]
  • Keene, T., Rankine, D., Evans, J., Southon, P., Kepert, C., Aitken, J., Sumby, C., Doonan, C. (2013). Solvent-modified dynamic porosity in chiral 3D kagome frameworks. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 42(22), 7871-7879. [More Information]
  • Keene, T., D'Alessandro, D., Kramer, K., Price, J., Price, D., Decurtins, S., Kepert, C. (2012). [V(16)O(38)(CN)](9-): A soluble mixed-valence redox-active building block with strong antiferromagnetic coupling. Inorganic Chemistry, 51(17), 9192-9199. [More Information]
  • Duriska, M., Neville, S., Moubaraki, B., Murray, K., Balde, C., Letard, J., Kepert, C., Batten, S. (2012). A family of discrete magnetically switchable nanoballs. ChemPlusChem, 77(8), 616-623. [More Information]
  • Das, A., Southon, P., Zhao, M., Kepert, C., Harris, A., D'Alessandro, D. (2012). Carbon dioxide adsorption by physisorption and chemisorption interactions in piperazine-grafted Ni2(dobdc) (dobdc = 1,4-dioxido-2,5-benzenedicarboxylate). Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 41(38), 11739-11744. [More Information]
  • Sciortino, N., Grunwald, K., Chastanet, G., Halder, G., Chapman, K., Letard, J., Kepert, C. (2012). Hysteretic Three-Step Spin Crossover in a Thermo- and Photochromic 3D Pillared Hofmann-type Metal-Organic Framework. Angewandte Chemie (International Edition), 51(40), 10154-10158. [More Information]
  • Yuan, P., Southon, P., Liu, Z., Kepert, C. (2012). Organosilane functionalization of halloysite nanotubes for enhanced loading and controlled release. Nanotechnology, 23(37), 375705. [More Information]
  • Li, F., Clegg, J., Goux-Capes, L., Chastanet, G., D'Alessandro, D., Letard, J., Kepert, C. (2011). A mixed-spin Molecular Square with a Hybrid [2x2]Grid/Metallocyclic Architecture. Angewandte Chemie (International Edition), 50(12), 2820-2823. [More Information]
  • Keene, T., Murphy, M., Price, J., Price, D., Kepert, C. (2011). A new modification of an old framework: Hofmann layers with unusual tetracyanidometallate groups. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 40(43), 11621-11628. [More Information]
  • Keene, T., Price, D., Kepert, C. (2011). Laboratory-based separation techniques for insoluble compound mixtures: methods for the purification of metal-organic framework materials. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 40(27), 7122-7126. [More Information]
  • Mulyana, Y., Lindoy, L., Kepert, C., McMurtrie, J., Parkin, A., Turner, P., Wei, G., Wilson, J. (2011). New metal organic frameworks incorporating the ditopic macrocyclic ligand dipyridyldibenzotetraaza[14]annulene. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 71(3-4), 455-462. [More Information]
  • Dunstan, M., Southon, P., Kepert, C., Hester, J., Kimpton, J., Ling, C. (2011). Phase diagram, chemical stability and physical properties of the solid-solution Ba(4)Nb(2-x)Ta(x)O(9). Journal of Solid State Chemistry, 184(10), 2648-2654. [More Information]
  • Southon, P., Price, D., Nielsen, P., McKenzie, C., Kepert, C. (2011). Reversible and Selective O2 Chemisorption in a Porous Metal-Organic Host Material. Journal of the American Chemical Society, 133(28), 10885-10891. [More Information]
  • Li, F., Clegg, J., D'Alessandro, D., Goux-Capes, L., Sciortino, N., Keene, T., Kepert, C. (2011). Self-assembled Co(II) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5',6'-pyrazine. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 40(45), 12388-12393. [More Information]
  • Li, F., Clegg, J., Price, D., Kepert, C. (2011). Self-Assembly of a Metallomacrocycle Templated by Iron(II). Inorganic Chemistry, 50(3), 726-728. [More Information]
  • Li, F., Clegg, J., Kepert, C. (2011). Structural diversity in coordination polymers constructed from a naphthalene-spaced dipyridyl ligand and iron(II) thiocyanate. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 71(3-4), 381-388. [More Information]
  • Peterson, V., Brown, C., Liu, Y., Kepert, C. (2011). Structural Study of D2 within the Trimodal Pore System of a Metal Organic Framework. The Journal of Physical Chemistry Part C: Nanomaterials and Interfaces, 115(17), 8851-8857. [More Information]
  • Lock, N., Wu, Y., Christensen, M., Cameron, L., Peterson, V., Bridgeman, A., Kepert, C., Iversen, B. (2010). Elucidating negative thermal expansion in MOF-5. The Journal of Physical Chemistry Part C: Nanomaterials and Interfaces, 114(39), 16181-16186.
  • Clegg, J., Iremonger, S., Hayter, M., Southon, P., Macquart, R., Duriska, M., Jensen, P., Turner, P., Jolliffe, K., Kepert, C., Lindoy, L., et al (2010). Hierarchical self-assembly of a chiral metal-organic framework displaying pronounced porosity. Angewandte Chemie (International Edition), 49(6), 1075-1078. [More Information]
  • Peterson, V., Kearley, G., Wu, Y., Ramirez-Cuesta, A., Kemner, E., Kepert, C. (2010). Local vibrational mechanism for negative thermal expansion: A combined neutron scattering and first-principles study. Angewandte Chemie (International Edition), 49(3), 585-588.
  • Wu, H., Simmons, J., Liu, Y., Brown, C., Wang, X., Ma, S., Peterson, V., Southon, P., Kepert, C., Zhou, H., et al (2010). Metal-organic frameworks with exceptionally high methane uptake: Where and how is methane stored? Chemistry: A European Journal, 16(17), 5205-5214. [More Information]
  • Yuan, A., Southon, P., Price, D., Kepert, C., Zhou, H., Liu, W. (2010). Syntheses, crystal structures, and the phase transformation of octacyanometallate-based Ln(+III)-W(+V) bimetallic assemblies with two-dimensional corrugated layers. European Journal of Inorganic Chemistry, 2010 (23), 3610-3614.
  • Amoore, J., Neville, S., Moubaraki, B., Iremonger, S., Murray, K., Letard, J., Kepert, C. (2010). Thermal- and light-induced spin crossover in a guest-dependent dinuclear iron(II) system. Chemistry: A European Journal, 16(6), 1973-1982. [More Information]
  • Phillips, A., Halder, G., Chapman, K., Goodwin, A., Kepert, C. (2010). Zero thermal expansion in a flexible, stable framework:  Tetramethylammonium copper(I) zinc(II) cyanide. Journal of the American Chemical Society, 132(1), 10-11. [More Information]
  • Duriska, M., Neville, S., Moubaraki, B., Cashion, J., Halder, G., Chapman, K., Balde, C., Letard, J., Murray, K., Kepert, C., et al (2009). A nanoscale molecular switch triggered by thermal, light, and guest perturbation. Angewandte Chemie (International Edition), 48(14), 2549-2552. [More Information]
  • Southon, P., Liu, L., Fellows, E., Price, D., Halder, G., Chapman, K., Moubaraki, B., Murray, K., Letard, J., Kepert, C. (2009). Dynamic interplay between spin-crossover and host-guest function in a nanoporous metal-organic framework material. Journal of the American Chemical Society, 131(31), 10998-11009. [More Information]
  • Neville, S., Halder, G., Chapman, K., Duriska, M., Moubaraki, B., Murray, K., Kepert, C. (2009). Guest tunable structure and spin crossover properties in a nanoporous coordination framework material. Journal of the American Chemical Society, 131(34), 12106-12108. [More Information]
  • Brown, C., Liu, Y., Yildirim, T., Peterson, V., Kepert, C. (2009). Hydrogen adsorption in HKUST-1: A combined inelastic neutron scattering and first-principles study. Nanotechnology, 20(20), 204025-1-204025-11.
  • Kepert, C. (2009). Supramolecular Magnetic Materials. Australian Journal of Chemistry: an international journal for chemical science, 62(9), 1079-1080.
  • Kumagai, H., Akita-Tanaka, M., Kawata, S., Inoue, K., Kepert, C., Kurmoo, M. (2009). Synthesis, crystal structures, and properties of molecular squares displaying hydrogen and pi-pi bonded networks. Crystal Growth and Design, 9(6), 2734-2741.
  • Duriska, M., Neville, S., Lu, J., Iremonger, S., Boas, J., Kepert, C., Batten, S. (2009). Systematic metal variation and solvent and hydrogen-gas storage in supramolecular nanoballs. Angewandte Chemie (International Edition), 48(47), 8919-8922. [More Information]
  • Goodwin, A., Kennedy, B., Kepert, C. (2009). Thermal expansion matching via framework flexibility in zinc dicyanometallates. Journal of the American Chemical Society, 131(18), 6334-6335. [More Information]
  • Iremonger, S., Southon, P., Kepert, C. (2008). A nanoporous chiral metal-organic framework material that exhibits reversible guest adsorption. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 2008 (44), 6103-6105.
  • Beves, J., Constable, E., Housecroft, C., Kepert, C., Neuburger, M., Price, D., Schaffner, S., Zampese, J. (2008). Curly-curly, loop-loop: homoleptic metal(II) complexes of pyridinecarbaldehyde 4'-(2,2':6',2''-terpyridyl)hydrazones and their coordination polymers. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 2008 (47), 6742-6751.
  • Halder, G., Chapman, K., Neville, S., Moubaraki, B., Murray, K., Letard, J., Kepert, C. (2008). Elucidating the Mechanism of a Two-Step Spin Transition in a Nanoporous Metal-Organic Framework. Journal of the American Chemical Society, 130(51), 17552-17562.
  • Beves, J., Bray, D., Clegg, J., Constable, E., Housecroft, C., Jolliffe, K., Kepert, C., Lindoy, L., Neuburger, M., Price, D., et al (2008). Expanding the 4,4'-bipyridine ligand: Structural variation in {M(pytpy)(2)}(2+) complexes (pytpy = 4'-(4-pyridyl)-2,2':6', 2"-terpyridine, M = Fe, Ni, Ru) and assembly of the hydrogen-bonded, one-dimensional polymer {[Ru(pytpy)(Hpytpy)]}(n)(3n+). Inorganica Chimica Acta, 361(9-10), 2582-2590. [More Information]
  • Yuan, P., Southon, P., Liu, Z., Green, M., Hook, J., Antill, S., Kepert, C. (2008). Functionalization of Halloysite Clay Nanotubes by Grafting with gamma-Aminopropyltriethoxysilane. The Journal of Physical Chemistry Part C: Nanomaterials and Interfaces, 112(40), 15742-15751.
  • Phillips, A., Goodwin, A., Halder, G., Southon, P., Kepert, C. (2008). Nanoporosity and exceptional negative thermal expansion in single-network cadmium cyanide. Angewandte Chemie (International Edition), 47(8), 1396-1399. [More Information]
  • Wu, Y., Kobayashi, A., Halder, G., Peterson, V., Chapman, K., Lock, N., Southon, P., Kepert, C. (2008). Negative Thermal Expansion in the Metal–Organic Framework Material Cu(3)(1,3,5-benzenetricarboxylate)(2). Angewandte Chemie (International Edition), 47(46), 8929-8932. [More Information]
  • Neville, S., Halder, G., Chapman, K., Duriska, M., Southon, P., Cashion, J., Letard, J., Moubaraki, B., Murray, K., Kepert, C. (2008). Single-crystal to single-crystal structural transformation and photomagnetic properties of a porous iron(II) spin-crossover framework. Journal of the American Chemical Society, 130(9), 2869-2876.
  • Neville, S., Leita, B., Halder, G., Kepert, C., Moubaraki, B., Letard, J., Murray, K. (2008). Understanding the two-step spin-transition phenomenon in iron(II) 1D chain materials. Chemistry: A European Journal, 14(32), 10123-10133. [More Information]
  • Beves, J., Dunphy, E., Constable, E., Housecroft, C., Kepert, C., Neuburger, M., Price, D., Schaffner, S. (2008). Vectorial property dependence in bis{4'-(n-pyridyl)-2,2':6',2"- terpyridine}iron(II) and ruthenium(II) complexes with n = 2, 3 and 4. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 2008 (3), 386-396.
  • Amoore, J., Kepert, C. (2007). 2,4,6-Tris(2-pyridylsulfanylmethyl)-1,3,5-triazine. Acta Crystallographica. Section E: Structure Reports Online, E63, o482-o484.
  • Neville, S., Moubaraki, B., Murray, K., Kepert, C. (2007). A thermal spin transition in a nanoporous iron(II) coordination framework material. Angewandte Chemie (International Edition), 46, 2059-2062. [More Information]
  • Leita, B., Neville, S., Halder, G., Moubaraki, B., Kepert, C., Letard, J., Murray, K. (2007). Anion-solvent dependence of bistability in a family of meridional N-donor-ligand-containing iron(II) spin crossover complexes. Inorganic Chemistry, 46(21), 8784-8795.
  • Liu, Y., Brown, C., Neumann, D., Peterson, V., Kepert, C. (2007). Inelastic neutron scattering of H2 adsorbed in HKUST-1. Journal of Alloys and Compounds, 446-447, 385-388. [More Information]
  • Ioppolo, J., Kepert, C., Price, D., Rendina, L. (2007). Mono- and di-nuclear gold(I) complexes containing 1,12-dicarba-closo-dodecaborance(12). Australian Journal of Chemistry: an international journal for chemical science, 60(11), 816-820.
  • Peterson, V., Liu, Y., Brown, C., Kepert, C. (2007). Structural characterization of D2 in Cu3(1,3,5-benzenetricarboxylate)2 using neutron powder diffraction. Materials Science Forum, 561-565(38), 1601-1604.
  • Moubaraki, B., Leita, B., Halder, G., Batten, S., Jensen, P., Smith, J., Cashion, J., Kepert, C., Letard, J., Murray, K. (2007). Structure, magnetism and photomagnetism of mixed-ligand tris(pyrazolyl)methane iron(II) spin crossover compounds. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 2007 (39), 4413-4426.
  • Zhou, H., Yuan, Z., Shen, X., Chen, Y., Price, D., Kepert, C. (2007). Synthesis, crystal structure and magnetic properties of a three-dimensional cyano-bridged heterometallic complex {NiII(Me6-[14]ane-N4}2[WIV(CN)8 dot 6H2O. Inorganic Chemistry Communications, 10(8), 940-943. [More Information]
  • Beves, J., Constable, E., Housecroft, C., Kepert, C., Neuburger, M., Price, D., Schaffner, S. (2007). The conjugate acid of bis{4'-(4-pyridyl)-2,2':6',2"-terpyridine} iron(II) as a self-complementary hydrogen-bonded building block. CrystEngComm, 9(11), 1073-1077.
  • Beves, J., Constable, E., Housecroft, C., Kepert, C., Price, D. (2007). The first example of a coordination polymer from the expanded 4,4'-bipyridine ligand [Ru(pytpy)2]2+ (pytpy = 4'-(4-pyridyl)-2,2':6',2''-terpyridine). CrystEngComm, 9(6), 456-459.
  • Sciortino, N., Kepert, C. (2006). 3-methyl-1-(3-methylpyridinium-4-yl)pyridinium dichloride monohydrate. Acta Crystallographica. Section E: Structure Reports Online, 62, O997-O998.
  • Kepert, C. (2006). Advanced functional properties in nanoporous coordination framework materials. Chemical Communications, 2006 (7), 695-700.
  • Chapman, K., Chupas, P., Kepert, C. (2006). Compositional dependence of negative thermal expansion in the Prussian blue analogues MII Pt-IV(CN)(6) (M = Mn, Fe, Co, Ni, Cu, Zn, Cd). Journal of the American Chemical Society, 128(21), 7009-7014.
  • Pretsch, T., Chapman, K., Halder, G., Kepert, C. (2006). Dehydration of the nanoporous coordination framework Er-III[Co-III(CN)6]center dot 4(H2O): single crystal to single crystal transformation and negative thermal expansion in Er-III[Co-III(CN)6]. Chemical Communications, (17), 1857-1859.
  • Chapman, K., Hagen, M., Kepert, C., Manuel, P. (2006). Low energy phonons in the NTE compounds Zn(CN)2 and ZnPt(CN)6. Physica B: Condensed Matter, 385-386(1), 60-62.
  • Peterson, V., Liu, Y., Brown, C., Kepert, C. (2006). Neutron Powder Diffraction Study of D-2 Sorption in Cu-3(1,3,5-benzenetricarboxylate)-2. Journal of the American Chemical Society, 128(49), 15578-15579.
  • Halder, G., Kepert, C. (2006). Single Crystal to Single Crystal Structural Transformations in Molecular Framework Materials. Australian Journal of Chemistry: an international journal for chemical science, 59(9), 597-604.
  • Amoore, J., Kepert, C., Cashion, J., Moubaraki, B., Neville, S., Murray, K. (2006). Structural and Magnetic Resolution of a Two-Step Full Spin-Crossover Transition in a Dinuclear Iron(II) Pyridyl-Bridged Compound. Chemistry: A European Journal, 12(32), 8220-8227. [More Information]
  • Junk, P., Kepert, C., Semenova, L., Skelton, B., White, A. (2006). The structural systematics of protonation of some important nitrogen-base ligands. I - Some univalent anion salts of doubly protonated 2, 2 ': 6 ', 2 ''-terpyridyl. Zeitschrift fuer Anorganische und Allgemeine Chemie, 632(7), 1293-1302. [More Information]
  • Effendy, N., Junk, P., Kepert, C., Louis, L., Morien, T., Skelton, B., White, A. (2006). The structural systematics of protonation of some important nitrogen-base ligands. III - Some (univalent) anion salts of some hindered unidentate nitrogen bases. Zeitschrift fuer Anorganische und Allgemeine Chemie, 632(7), 1312-1325. [More Information]
  • Amoore, J., Kepert, C. (2005). 2,4,6-Tris(4-pyridylmethylsulfanyl)-1,3,5-triazine monohydrate. Acta Crystallographica. Section E: Structure Reports Online, 61(6), O1900-O1901.
  • Amoore, J., Kepert, C. (2005). 4-(4-pyridylamino)pyridinium isophthalate. Acta Crystallographica. Section E: Structure Reports Online, 61, O3937-O3938.
  • Halder, G., Neville, S., Kepert, C. (2005). A highly distorted (10,3)-a coordination framework constructed from alternating T-shaped and trigonal nodes. CrystEngComm, 7, 266-268.
  • Halder, G., Kepert, C. (2005). A three-dimensional hydrogen-bonded coordination framework: catena-poly[[[tetraaquairon(II)]-mu-4,4 '-bipyridine] benzene-1,4-dicarboxylate]. Acta Crystallographica. Section E: Structure Reports Online, 61, M113-M114.
  • Chapman, K., Chupas, P., Kepert, C. (2005). Direct observation of a transverse vibrational mechanism for negative thermal expansion in Zn(CN)2: An atomic pair distribution function analysis. Journal of the American Chemical Society, 127(44), 15630-15636.
  • Goodwin, A., Chapman, K., Kepert, C. (2005). Guest-dependent negative thermal expansion in nanoporous Prussian Blue analogues MIIPtIV(CN)6 · x{H 2O} (0 [less-than or equal to] X [less-than or equal to] 2; M = Zn, Cd). Journal of the American Chemical Society, 127(51), 17980-17981.
  • Halder, G., Kepert, C. (2005). In situ single-crystal X-ray diffraction studies of desorption and sorption in a flexible nanoporous molecular framework material. Journal of the American Chemical Society, 127(21), 7891-7900.
  • Halder, G., Kepert, C. (2005). Iron(II) molecular framework materials with 4,4 '-azopyridine. Australian Journal of Chemistry: an international journal for chemical science, 58(5), 311-314.
  • Goodwin, A., Kepert, C. (2005). Negative thermal expansion and low-frequency modes in cyanide-bridged framework materials. Physical Review B (Condensed Matter and Materials Physics), 71(14), 140301-1-140301-4.
  • Mulyana, Y., Kepert, C., Lindoy, L., McMurtrie, J. (2005). New cadmium(II) and iron(II) coordination frameworks incorporating a di(4-pyridyl)isoindoline ligand. European Journal of Inorganic Chemistry, 2005 (12), 2470-2475. [More Information]
  • Mulyana, Y., Kepert, C., Lindoy, L., Parkin, A., Turner, P. (2005). New cobalt(II) and zinc(II) coordination frameworks incorporating a pyridyl-pyrazole ditopic ligand. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 2005 (9), 1598-1601.
  • Kurmoo, M., Kumagai, H., Chapman, K., Kepert, C. (2005). Reversible ferromagnetic-antiferromagnetic transformation upon dehydration-hydration of the nanoporous coordination framework, [Co-3(OH)(2)(C4O4)(2)]center dot 3H(2)O. Chemical Communications, 2005 (24), 3012-3014.
  • Chapman, K., Southon, P., Weeks, C., Kepert, C. (2005). Reversible hydrogen gas uptake in nanoporous Prussian Blue analogues. Chemical Communications, 2005 (26), 3322-3324.
  • Chapman, K., Chupas, P., Kepert, C. (2005). Selective recovery of dynamic guest structure, in a nanoporous Prussian blue through in situ X-ray diffraction: A differential pair distribution function analysis. Journal of the American Chemical Society, 127(32), 11232-11233.
  • Rujiwatra, A., Mander, G., Kepert, C., Rosseinsky, M. (2005). Synthesis and characterization of subcell-supercell related ethylenediamine-pillared zinc hydroxysulfates. Crystal Growth and Design, 5(1), 183-189.
  • Ganesan, P., Kepert, C. (2004). Nanoporosity Of An Interpenetrated Nbo-Type Molecular Framework Studied By Single Crystal X-Ray Diffraction. Chemical Communications, (19), 2168-2169.
  • Kumagai, H., Chapman, K., Kepert, C., Kurmoo, M. (2003). Binary metal(II) - pyromellitate coordinates polymers, M2(pm) (M=Co, Fe, Mn): synthesis, structures and magnetic properties. Polyhedron, 22(14-17), 1921-1927.
  • Kurmoo, M., Kumagai, H., Neville, S., Kepert, C. (2003). Reversible guest exchange and ferrimagnetism (Tc = 60.5 K) in a porous cobalt(II)-hydroxide layer structure pillared with trans-1,4-cyclohexanedicarboxylate. Inorganic Chemistry, 42(21), 6709-6722.
  • Kumagai, H., Kepert, C., Kurmoo, M. (2002). Construction of Hydrogen-Bonded and Coordination-Bonded Networks of Cobalt(II) with Pyromellitate: Synthesis, Structures, and Magnetic Properties. Inorganic Chemistry, 41(13), 3410-3422.
  • Cussen, E., Claridge, J., Rosseinsky, M., Kepert, C. (2002). Flexible Sorption and Transformation Behavior in a Microporous Metal-Organic Framework. Journal of the American Chemical Society, 124(32), 9574-9581.
  • Halder, G., Kepert, C., Moubaraki, B., Murray, K., Cashion, J. (2002). Guest-Dependent Spin Crossover in a Nanoporous Molecular Framework Material. Science, 298(29 Nov), 1762-1765.
  • Kepert, C., Fletcher, A., Cussen, E., Prior, N., Rosseinsky, M., Thomas, K. (2001). Adsorption dynamics of gases and vapors on the nanoporous metal organic framework material Ni2(4,4'-bipyridine)3(NO3)4: Guest modification of host sorption behavior. Journal of the American Chemical Society, 123, 10001-10011.
  • Kepert, C., Rujiwatra, A., Claridge, J., Rosseinsky, M., Kumagai, H., Kurmoo, M. (2001). Layered cobalt hydroxysulfates with both rigid and flexible organic pillars: Synthesis, structure, porosity, and cooperative magnetism. Journal of the American Chemical Society, 123, 10584-10594.
  • Kepert, C., Figgis, B., Sobolev, A., Kurmoo, M. (2001). MEM(TCNQ)2 at room temperature and 10 K, and the absence of a spin-Peierls transition. Acta Crystallographica. Section C: Crystal Structure Communications, C57, 991-993.
  • Kepert, C., Jestadt, T., Kurmoo, M., Blundell,, S., Pratt, F., Husmann,, A., Prassides, K., Lovett,, B., Marshall, I., et, A. (2001). Muon-spin-rotation and magnetization study of metal-organic magnets based on the dicyanamide anion. Journal of Physics: Condensed Matter, 13, 2263-2270.

Conferences

  • Cameron, L., Lock, N., Kepert, C. (2009). An investigation of negative thermal expansion in metal-organic frameworks. 26th Biennial Conference of the Society of Crystallographers in Australia and New Zealand, N/A: N/A.
  • Chadbourne, J., Price, D., Liu, L., Kepert, C. (2009). NbO-type Prussian blue analogues as candidates for hydrogen storage in coordination framework materials. 26th Biennial Conference of the Society of Crystallographers in Australia and New Zealand, N/A: N/A.
  • Fellows, E., Southon, P., Price, D., Moubaraki, B., Kepert, C. (2009). Synchrotron-PXRD studies of guest-influenced spin crossover in Fe(pz)Ni(CN)4. 26th Biennial Conference of the Society of Crystallographers in Australia and New Zealand, N/A: N/A.

Patents

  • Kepert, C., Goodwin, A. (2007). Anomalous Expansion Materials. Patent No. 537439. New Zealand.

2014

  • Sciortino, N., Neville, S., Desplanches, C., Letard, J., Martinez, V., Real, J., Moubaraki, B., Murray, K., Kepert, C. (2014). An investigation of photo- and pressure-induced effects in a pair of isostructural two-dimensional spin-crossover framework materials. Chemistry: A European Journal, 20(24), 7448-7457. [More Information]
  • Yuan, A., Zhou, H., Diao, G., Southon, P., Kepert, C., Liu, L. (2014). Gas and vapor adsorption in octacyanometallate-based frameworks Mn2[M(CN)8] (M = W, Mo) with exposed Mn2+ sites. International Journal of Hydrogen Energy, 39(2), 884-889. [More Information]
  • Peterson, V., Southon, P., Halder, G., Price, D., Bevitt, J., Kepert, C. (2014). Guest Adsorption in the Nanoporous Metal-Organic Framework Cu3(1,3,5-Benzenetricarboxylate)2: Combined In Situ X-ray Diffraction and Vapor Sorption. Chemistry of Materials, 26(16), 4712-4723. [More Information]
  • Faust, T., Usov, P., D'Alessandro, D., Kepert, C. (2014). Highly unusual interpenetration isomers of electroactive nickel bis(dithiolene) coordination frameworks. Chemical Communications, 50(84), 12772-12774. [More Information]
  • Ogilvie, S., Duyker, S., Southon, P., Peterson, V., Kepert, C. (2014). Host-guest adsorption behavior of deuterated methane and molecular oxygen in a porous rare-earth metal-organic framework. Powder Diffraction, 128(11), 1-6. [More Information]
  • Wu, Y., Peterson, V., Luks, E., Darwish, T., Kepert, C. (2014). Interpenetration as a mechanism for negative thermal expansion in the metal-organic framework Cu3(btb)2 (MOF-14). Angewandte Chemie (International Edition), 53(20), 5175-5178. [More Information]
  • Murphy, M., Keene, T., Price, J., D'Alessandro, D., Kepert, C. (2014). Magnetic and electronic properties of three new hetero-bimetallic coordination frameworks [Ru2(02CR)4][Au(CN)2] (R = benzoic acid, Furan-2-carboxylate, or Thiophen-2-carboxylate). Australian Journal of Chemistry: an international journal for chemical science, 67(11), 1607-1611. [More Information]
  • Murphy, M., Usov, P., Rizzuto, F., Kepert, C., D'Alessandro, D. (2014). Magnetic, electrochemical and optical properties of a sulfate-bridged Co(II) imidazole dimer. New Journal of Chemistry, 38(12), 5856-5860. [More Information]
  • Keene, T., Murphy, M., Price, J., Sciortino, N., Southon, P., Kepert, C. (2014). Multifunctional MOFs through CO2 fixation: a metamagnetic kagome lattice with uniaxial zero thermal expansion and reversible guest sorption. Dalton Transactions, 43(39), 14766-14771. [More Information]
  • Sundberg, J., Cameron, L., Southon, P., Kepert, C., McKenzie, C. (2014). Oxygen chemisorption/desorption in a reversible single-crystal-to-single-crystal transformation. Chemical Science, 5(10), 4017-4025. [More Information]
  • Clements, J., Price, J., Neville, S., Kepert, C. (2014). Perturbation of Spin Crossover Behavior by Covalent Post-Synthetic Modification of a Porous Metal-Organic Framework. Angewandte Chemie (International Edition), 53(38), 10164-10168. [More Information]
  • Cowan, M., Miller, R., Southon, P., Price, J., Yazaydin, O., Lane, J., Kepert, C., Brooker, S. (2014). Selective gas adsorption in a pair of robust isostructural MOFs differing in framework charge and anion loading. Inorganic Chemistry, 53(22), 12076-12083. [More Information]
  • Reichel, F., Clegg, J., Gloe, K., Gloe, K., Weigand, J., Reynolds, J., Li, C., Aldrich-Wright, J., Kepert, C., Lindoy, L., et al (2014). Self-assembly of an imidazolate-bridged Fe(III)/Cu(II) heterometallic cage. Inorganic Chemistry, 53(2), 688-690. [More Information]
  • Li, F., Sciortino, N., Clegg, J., Neville, S., Kepert, C. (2014). Self-assembly of an octanuclear high-spin FeII molecular cage. Australian Journal of Chemistry: an international journal for chemical science, 67(11), 1625-1628. [More Information]
  • Klein, M., Sciortino, N., Ragon, F., Housecroft, C., Kepert, C., Neville, S. (2014). Spin crossover intermediate plateau stabilization in a flexible 2-D Hofmann-type coordination polymer. Chemical Communications, 50(29), 3838-3840. [More Information]
  • Pages, B., Li, F., Wormell, P., Ang, D., Clegg, J., Kepert, C., Spare, L., Danchaiwijit, S., Aldrich-Wright, J. (2014). Synthesis and analysis of the anticancer activity of platinum(II) complexes incorporating dipyridoquinoxaline variants. Dalton Transactions, 43(41), 15566-15575. [More Information]
  • Ragon, F., Yaksi, K., Sciortino, N., Chastanet, G., Letard, J., D'Alessandro, D., Kepert, C., Neville, S. (2014). Thermal spin crossover behaviour of two-dimensional Hofmann-type coordination polymers incorporating photoactive ligands. Australian Journal of Chemistry: an international journal for chemical science, 67(11), 1563-1573. [More Information]
  • Sciortino, N., Neville, S., Letard, J., Moubaraki, B., Murray, K., Kepert, C. (2014). Thermal- and light-induced spin-crossover bistability in a disrupted Hofmann-type 3D framework. Inorganic Chemistry, 53(15), 7886-7893. [More Information]
  • Duyker, S., Halder, G., Southon, P., Price, D., Edwards, A., Peterson, V., Kepert, C. (2014). Topotactic structural conversion and hydration-dependent thermal expansion in robust LnMIII(CN)6 ·nH2O and flexible ALnFeII(CN)6·nH2O frameworks (A = Li, Na, K; Ln = La-Lu, Y; M = Co, Fe; 0 ≤ n ≥ 5). Chemical Science, 5(9), 3409-3417. [More Information]

2013

  • Neville, S., Halder, G., Murray, K., Moubaraki, B., Kepert, C. (2013). A family of three-dimensional molecular framework materials containing the three-connecting ligands 2,4,6-tris(n'-pyridyl)-1,3,5-triazine: 3-tpt and 4-tpt. Australian Journal of Chemistry: an international journal for chemical science, 66(4), 452-463. [More Information]
  • Murphy, M., D'Alessandro, D., Kepert, C. (2013). A porous Mn(v) coordination framework with PtS topology: assessment of the influence of a terminal nitride on CO(2) sorption. Dalton Transactions, 42(37), 13308-13310. [More Information]
  • Das, A., Choucair, M., Southon, P., Mason, J., Zhao, M., Kepert, C., Harris, A., D'Alessandro, D. (2013). Application of the piperazine-grafted CuBTTri metal-organic framework in postcombustion carbon dioxide capture. Microporous and Mesoporous Materials, 174(2013), 74-80. [More Information]
  • Lyndon, R., Konstas, K., Ladewig, B., Southon, P., Kepert, C., Hill, M. (2013). Dynamic Photo-Switching in Metal–Organic Frameworks as a Route to Low-Energy Carbon Dioxide Capture and Release. Angewandte Chemie (International Edition), 52(13), 3695-3698. [More Information]
  • Lock, N., Christensen, M., Kepert, C., Iversen, B. (2013). Effect of gas pressure on negative thermal expansion in MOF-5. Chemical Communications, 49(8), 789-791. [More Information]
  • Leong, C., Faust, T., Turner, P., Usov, P., Kepert, C., Babarao, R., Thornton, A., D'Alessandro, D. (2013). Enhancing selective CO(2) adsorption via chemical reduction of a redox-active metal-organic framework. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 42(27), 9831-9839. [More Information]
  • Ogilvie, S., Duyker, S., Southon, P., Peterson, V., Kepert, C. (2013). Identification of bridged CO(2) binding in a Prussian blue analogue using neutron powder diffraction. Chemical Communications, 49(82), 9404-9406. [More Information]
  • Duyker, S., Peterson, V., Kearley, G., Ramirez-Cuesta, A., Kepert, C. (2013). Negative thermal expansion in LnCo(CN)6 (Ln=La, Pr, Sm, Ho, Lu, Y): Mechanisms and compositional trends. Angewandte Chemie (International Edition), 52(20), 5266-5270. [More Information]
  • Lock, N., Christensen, M., Wu, Y., Peterson, V., Thomsen, M., Piltz, R., Ramirez-Cuesta, A., McIntyre, G., Norén, K., Kutteh, R., Kepert, C., et al (2013). Scrutinizing negative thermal expansion in MOF-5 by scattering techniques and ab initio calculations. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 42(6), 1996-2007. [More Information]
  • Keene, T., Rankine, D., Evans, J., Southon, P., Kepert, C., Aitken, J., Sumby, C., Doonan, C. (2013). Solvent-modified dynamic porosity in chiral 3D kagome frameworks. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 42(22), 7871-7879. [More Information]

2012

  • Keene, T., D'Alessandro, D., Kramer, K., Price, J., Price, D., Decurtins, S., Kepert, C. (2012). [V(16)O(38)(CN)](9-): A soluble mixed-valence redox-active building block with strong antiferromagnetic coupling. Inorganic Chemistry, 51(17), 9192-9199. [More Information]
  • Duriska, M., Neville, S., Moubaraki, B., Murray, K., Balde, C., Letard, J., Kepert, C., Batten, S. (2012). A family of discrete magnetically switchable nanoballs. ChemPlusChem, 77(8), 616-623. [More Information]
  • Das, A., Southon, P., Zhao, M., Kepert, C., Harris, A., D'Alessandro, D. (2012). Carbon dioxide adsorption by physisorption and chemisorption interactions in piperazine-grafted Ni2(dobdc) (dobdc = 1,4-dioxido-2,5-benzenedicarboxylate). Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 41(38), 11739-11744. [More Information]
  • Sciortino, N., Grunwald, K., Chastanet, G., Halder, G., Chapman, K., Letard, J., Kepert, C. (2012). Hysteretic Three-Step Spin Crossover in a Thermo- and Photochromic 3D Pillared Hofmann-type Metal-Organic Framework. Angewandte Chemie (International Edition), 51(40), 10154-10158. [More Information]
  • Yuan, P., Southon, P., Liu, Z., Kepert, C. (2012). Organosilane functionalization of halloysite nanotubes for enhanced loading and controlled release. Nanotechnology, 23(37), 375705. [More Information]

2011

  • Li, F., Clegg, J., Goux-Capes, L., Chastanet, G., D'Alessandro, D., Letard, J., Kepert, C. (2011). A mixed-spin Molecular Square with a Hybrid [2x2]Grid/Metallocyclic Architecture. Angewandte Chemie (International Edition), 50(12), 2820-2823. [More Information]
  • Keene, T., Murphy, M., Price, J., Price, D., Kepert, C. (2011). A new modification of an old framework: Hofmann layers with unusual tetracyanidometallate groups. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 40(43), 11621-11628. [More Information]
  • Keene, T., Price, D., Kepert, C. (2011). Laboratory-based separation techniques for insoluble compound mixtures: methods for the purification of metal-organic framework materials. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 40(27), 7122-7126. [More Information]
  • Kepert, C. (2011). Metal-organic framework materials. In Duncan W. Bruce; Dermot OHare; Richard I. Walton (Eds.), Porous Materials, (pp. 1-67). United Kingdom: John Wiley & Sons.
  • Mulyana, Y., Lindoy, L., Kepert, C., McMurtrie, J., Parkin, A., Turner, P., Wei, G., Wilson, J. (2011). New metal organic frameworks incorporating the ditopic macrocyclic ligand dipyridyldibenzotetraaza[14]annulene. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 71(3-4), 455-462. [More Information]
  • Dunstan, M., Southon, P., Kepert, C., Hester, J., Kimpton, J., Ling, C. (2011). Phase diagram, chemical stability and physical properties of the solid-solution Ba(4)Nb(2-x)Ta(x)O(9). Journal of Solid State Chemistry, 184(10), 2648-2654. [More Information]
  • Southon, P., Price, D., Nielsen, P., McKenzie, C., Kepert, C. (2011). Reversible and Selective O2 Chemisorption in a Porous Metal-Organic Host Material. Journal of the American Chemical Society, 133(28), 10885-10891. [More Information]
  • Li, F., Clegg, J., D'Alessandro, D., Goux-Capes, L., Sciortino, N., Keene, T., Kepert, C. (2011). Self-assembled Co(II) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5',6'-pyrazine. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 40(45), 12388-12393. [More Information]
  • Li, F., Clegg, J., Price, D., Kepert, C. (2011). Self-Assembly of a Metallomacrocycle Templated by Iron(II). Inorganic Chemistry, 50(3), 726-728. [More Information]
  • Li, F., Clegg, J., Kepert, C. (2011). Structural diversity in coordination polymers constructed from a naphthalene-spaced dipyridyl ligand and iron(II) thiocyanate. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 71(3-4), 381-388. [More Information]
  • Peterson, V., Brown, C., Liu, Y., Kepert, C. (2011). Structural Study of D2 within the Trimodal Pore System of a Metal Organic Framework. The Journal of Physical Chemistry Part C: Nanomaterials and Interfaces, 115(17), 8851-8857. [More Information]

2010

  • Lock, N., Wu, Y., Christensen, M., Cameron, L., Peterson, V., Bridgeman, A., Kepert, C., Iversen, B. (2010). Elucidating negative thermal expansion in MOF-5. The Journal of Physical Chemistry Part C: Nanomaterials and Interfaces, 114(39), 16181-16186.
  • Clegg, J., Iremonger, S., Hayter, M., Southon, P., Macquart, R., Duriska, M., Jensen, P., Turner, P., Jolliffe, K., Kepert, C., Lindoy, L., et al (2010). Hierarchical self-assembly of a chiral metal-organic framework displaying pronounced porosity. Angewandte Chemie (International Edition), 49(6), 1075-1078. [More Information]
  • Peterson, V., Kearley, G., Wu, Y., Ramirez-Cuesta, A., Kemner, E., Kepert, C. (2010). Local vibrational mechanism for negative thermal expansion: A combined neutron scattering and first-principles study. Angewandte Chemie (International Edition), 49(3), 585-588.
  • Wu, H., Simmons, J., Liu, Y., Brown, C., Wang, X., Ma, S., Peterson, V., Southon, P., Kepert, C., Zhou, H., et al (2010). Metal-organic frameworks with exceptionally high methane uptake: Where and how is methane stored? Chemistry: A European Journal, 16(17), 5205-5214. [More Information]
  • Yuan, A., Southon, P., Price, D., Kepert, C., Zhou, H., Liu, W. (2010). Syntheses, crystal structures, and the phase transformation of octacyanometallate-based Ln(+III)-W(+V) bimetallic assemblies with two-dimensional corrugated layers. European Journal of Inorganic Chemistry, 2010 (23), 3610-3614.
  • Amoore, J., Neville, S., Moubaraki, B., Iremonger, S., Murray, K., Letard, J., Kepert, C. (2010). Thermal- and light-induced spin crossover in a guest-dependent dinuclear iron(II) system. Chemistry: A European Journal, 16(6), 1973-1982. [More Information]
  • Phillips, A., Halder, G., Chapman, K., Goodwin, A., Kepert, C. (2010). Zero thermal expansion in a flexible, stable framework:  Tetramethylammonium copper(I) zinc(II) cyanide. Journal of the American Chemical Society, 132(1), 10-11. [More Information]

2009

  • Duriska, M., Neville, S., Moubaraki, B., Cashion, J., Halder, G., Chapman, K., Balde, C., Letard, J., Murray, K., Kepert, C., et al (2009). A nanoscale molecular switch triggered by thermal, light, and guest perturbation. Angewandte Chemie (International Edition), 48(14), 2549-2552. [More Information]
  • Cameron, L., Lock, N., Kepert, C. (2009). An investigation of negative thermal expansion in metal-organic frameworks. 26th Biennial Conference of the Society of Crystallographers in Australia and New Zealand, N/A: N/A.
  • Southon, P., Liu, L., Fellows, E., Price, D., Halder, G., Chapman, K., Moubaraki, B., Murray, K., Letard, J., Kepert, C. (2009). Dynamic interplay between spin-crossover and host-guest function in a nanoporous metal-organic framework material. Journal of the American Chemical Society, 131(31), 10998-11009. [More Information]
  • Neville, S., Halder, G., Chapman, K., Duriska, M., Moubaraki, B., Murray, K., Kepert, C. (2009). Guest tunable structure and spin crossover properties in a nanoporous coordination framework material. Journal of the American Chemical Society, 131(34), 12106-12108. [More Information]
  • Brown, C., Liu, Y., Yildirim, T., Peterson, V., Kepert, C. (2009). Hydrogen adsorption in HKUST-1: A combined inelastic neutron scattering and first-principles study. Nanotechnology, 20(20), 204025-1-204025-11.
  • Chadbourne, J., Price, D., Liu, L., Kepert, C. (2009). NbO-type Prussian blue analogues as candidates for hydrogen storage in coordination framework materials. 26th Biennial Conference of the Society of Crystallographers in Australia and New Zealand, N/A: N/A.
  • Kepert, C. (2009). Supramolecular Magnetic Materials. Australian Journal of Chemistry: an international journal for chemical science, 62(9), 1079-1080.
  • Fellows, E., Southon, P., Price, D., Moubaraki, B., Kepert, C. (2009). Synchrotron-PXRD studies of guest-influenced spin crossover in Fe(pz)Ni(CN)4. 26th Biennial Conference of the Society of Crystallographers in Australia and New Zealand, N/A: N/A.
  • Kumagai, H., Akita-Tanaka, M., Kawata, S., Inoue, K., Kepert, C., Kurmoo, M. (2009). Synthesis, crystal structures, and properties of molecular squares displaying hydrogen and pi-pi bonded networks. Crystal Growth and Design, 9(6), 2734-2741.
  • Duriska, M., Neville, S., Lu, J., Iremonger, S., Boas, J., Kepert, C., Batten, S. (2009). Systematic metal variation and solvent and hydrogen-gas storage in supramolecular nanoballs. Angewandte Chemie (International Edition), 48(47), 8919-8922. [More Information]
  • Goodwin, A., Kennedy, B., Kepert, C. (2009). Thermal expansion matching via framework flexibility in zinc dicyanometallates. Journal of the American Chemical Society, 131(18), 6334-6335. [More Information]

2008

  • Iremonger, S., Southon, P., Kepert, C. (2008). A nanoporous chiral metal-organic framework material that exhibits reversible guest adsorption. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 2008 (44), 6103-6105.
  • Beves, J., Constable, E., Housecroft, C., Kepert, C., Neuburger, M., Price, D., Schaffner, S., Zampese, J. (2008). Curly-curly, loop-loop: homoleptic metal(II) complexes of pyridinecarbaldehyde 4'-(2,2':6',2''-terpyridyl)hydrazones and their coordination polymers. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 2008 (47), 6742-6751.
  • Halder, G., Chapman, K., Neville, S., Moubaraki, B., Murray, K., Letard, J., Kepert, C. (2008). Elucidating the Mechanism of a Two-Step Spin Transition in a Nanoporous Metal-Organic Framework. Journal of the American Chemical Society, 130(51), 17552-17562.
  • Beves, J., Bray, D., Clegg, J., Constable, E., Housecroft, C., Jolliffe, K., Kepert, C., Lindoy, L., Neuburger, M., Price, D., et al (2008). Expanding the 4,4'-bipyridine ligand: Structural variation in {M(pytpy)(2)}(2+) complexes (pytpy = 4'-(4-pyridyl)-2,2':6', 2"-terpyridine, M = Fe, Ni, Ru) and assembly of the hydrogen-bonded, one-dimensional polymer {[Ru(pytpy)(Hpytpy)]}(n)(3n+). Inorganica Chimica Acta, 361(9-10), 2582-2590. [More Information]
  • Yuan, P., Southon, P., Liu, Z., Green, M., Hook, J., Antill, S., Kepert, C. (2008). Functionalization of Halloysite Clay Nanotubes by Grafting with gamma-Aminopropyltriethoxysilane. The Journal of Physical Chemistry Part C: Nanomaterials and Interfaces, 112(40), 15742-15751.
  • Phillips, A., Goodwin, A., Halder, G., Southon, P., Kepert, C. (2008). Nanoporosity and exceptional negative thermal expansion in single-network cadmium cyanide. Angewandte Chemie (International Edition), 47(8), 1396-1399. [More Information]
  • Wu, Y., Kobayashi, A., Halder, G., Peterson, V., Chapman, K., Lock, N., Southon, P., Kepert, C. (2008). Negative Thermal Expansion in the Metal–Organic Framework Material Cu(3)(1,3,5-benzenetricarboxylate)(2). Angewandte Chemie (International Edition), 47(46), 8929-8932. [More Information]
  • Neville, S., Halder, G., Chapman, K., Duriska, M., Southon, P., Cashion, J., Letard, J., Moubaraki, B., Murray, K., Kepert, C. (2008). Single-crystal to single-crystal structural transformation and photomagnetic properties of a porous iron(II) spin-crossover framework. Journal of the American Chemical Society, 130(9), 2869-2876.
  • Neville, S., Leita, B., Halder, G., Kepert, C., Moubaraki, B., Letard, J., Murray, K. (2008). Understanding the two-step spin-transition phenomenon in iron(II) 1D chain materials. Chemistry: A European Journal, 14(32), 10123-10133. [More Information]
  • Beves, J., Dunphy, E., Constable, E., Housecroft, C., Kepert, C., Neuburger, M., Price, D., Schaffner, S. (2008). Vectorial property dependence in bis{4'-(n-pyridyl)-2,2':6',2"- terpyridine}iron(II) and ruthenium(II) complexes with n = 2, 3 and 4. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 2008 (3), 386-396.

2007

  • Amoore, J., Kepert, C. (2007). 2,4,6-Tris(2-pyridylsulfanylmethyl)-1,3,5-triazine. Acta Crystallographica. Section E: Structure Reports Online, E63, o482-o484.
  • Neville, S., Moubaraki, B., Murray, K., Kepert, C. (2007). A thermal spin transition in a nanoporous iron(II) coordination framework material. Angewandte Chemie (International Edition), 46, 2059-2062. [More Information]
  • Leita, B., Neville, S., Halder, G., Moubaraki, B., Kepert, C., Letard, J., Murray, K. (2007). Anion-solvent dependence of bistability in a family of meridional N-donor-ligand-containing iron(II) spin crossover complexes. Inorganic Chemistry, 46(21), 8784-8795.
  • Kepert, C., Goodwin, A. (2007). Anomalous Expansion Materials. Patent No. 537439. New Zealand.
  • Liu, Y., Brown, C., Neumann, D., Peterson, V., Kepert, C. (2007). Inelastic neutron scattering of H2 adsorbed in HKUST-1. Journal of Alloys and Compounds, 446-447, 385-388. [More Information]
  • Ioppolo, J., Kepert, C., Price, D., Rendina, L. (2007). Mono- and di-nuclear gold(I) complexes containing 1,12-dicarba-closo-dodecaborance(12). Australian Journal of Chemistry: an international journal for chemical science, 60(11), 816-820.
  • Peterson, V., Liu, Y., Brown, C., Kepert, C. (2007). Structural characterization of D2 in Cu3(1,3,5-benzenetricarboxylate)2 using neutron powder diffraction. Materials Science Forum, 561-565(38), 1601-1604.
  • Moubaraki, B., Leita, B., Halder, G., Batten, S., Jensen, P., Smith, J., Cashion, J., Kepert, C., Letard, J., Murray, K. (2007). Structure, magnetism and photomagnetism of mixed-ligand tris(pyrazolyl)methane iron(II) spin crossover compounds. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 2007 (39), 4413-4426.
  • Zhou, H., Yuan, Z., Shen, X., Chen, Y., Price, D., Kepert, C. (2007). Synthesis, crystal structure and magnetic properties of a three-dimensional cyano-bridged heterometallic complex {NiII(Me6-[14]ane-N4}2[WIV(CN)8 dot 6H2O. Inorganic Chemistry Communications, 10(8), 940-943. [More Information]
  • Beves, J., Constable, E., Housecroft, C., Kepert, C., Neuburger, M., Price, D., Schaffner, S. (2007). The conjugate acid of bis{4'-(4-pyridyl)-2,2':6',2"-terpyridine} iron(II) as a self-complementary hydrogen-bonded building block. CrystEngComm, 9(11), 1073-1077.
  • Beves, J., Constable, E., Housecroft, C., Kepert, C., Price, D. (2007). The first example of a coordination polymer from the expanded 4,4'-bipyridine ligand [Ru(pytpy)2]2+ (pytpy = 4'-(4-pyridyl)-2,2':6',2''-terpyridine). CrystEngComm, 9(6), 456-459.

2006

  • Sciortino, N., Kepert, C. (2006). 3-methyl-1-(3-methylpyridinium-4-yl)pyridinium dichloride monohydrate. Acta Crystallographica. Section E: Structure Reports Online, 62, O997-O998.
  • Kepert, C. (2006). Advanced functional properties in nanoporous coordination framework materials. Chemical Communications, 2006 (7), 695-700.
  • Chapman, K., Chupas, P., Kepert, C. (2006). Compositional dependence of negative thermal expansion in the Prussian blue analogues MII Pt-IV(CN)(6) (M = Mn, Fe, Co, Ni, Cu, Zn, Cd). Journal of the American Chemical Society, 128(21), 7009-7014.
  • Pretsch, T., Chapman, K., Halder, G., Kepert, C. (2006). Dehydration of the nanoporous coordination framework Er-III[Co-III(CN)6]center dot 4(H2O): single crystal to single crystal transformation and negative thermal expansion in Er-III[Co-III(CN)6]. Chemical Communications, (17), 1857-1859.
  • Chapman, K., Hagen, M., Kepert, C., Manuel, P. (2006). Low energy phonons in the NTE compounds Zn(CN)2 and ZnPt(CN)6. Physica B: Condensed Matter, 385-386(1), 60-62.
  • Peterson, V., Liu, Y., Brown, C., Kepert, C. (2006). Neutron Powder Diffraction Study of D-2 Sorption in Cu-3(1,3,5-benzenetricarboxylate)-2. Journal of the American Chemical Society, 128(49), 15578-15579.
  • Halder, G., Kepert, C. (2006). Single Crystal to Single Crystal Structural Transformations in Molecular Framework Materials. Australian Journal of Chemistry: an international journal for chemical science, 59(9), 597-604.
  • Amoore, J., Kepert, C., Cashion, J., Moubaraki, B., Neville, S., Murray, K. (2006). Structural and Magnetic Resolution of a Two-Step Full Spin-Crossover Transition in a Dinuclear Iron(II) Pyridyl-Bridged Compound. Chemistry: A European Journal, 12(32), 8220-8227. [More Information]
  • Junk, P., Kepert, C., Semenova, L., Skelton, B., White, A. (2006). The structural systematics of protonation of some important nitrogen-base ligands. I - Some univalent anion salts of doubly protonated 2, 2 ': 6 ', 2 ''-terpyridyl. Zeitschrift fuer Anorganische und Allgemeine Chemie, 632(7), 1293-1302. [More Information]
  • Effendy, N., Junk, P., Kepert, C., Louis, L., Morien, T., Skelton, B., White, A. (2006). The structural systematics of protonation of some important nitrogen-base ligands. III - Some (univalent) anion salts of some hindered unidentate nitrogen bases. Zeitschrift fuer Anorganische und Allgemeine Chemie, 632(7), 1312-1325. [More Information]

2005

  • Amoore, J., Kepert, C. (2005). 2,4,6-Tris(4-pyridylmethylsulfanyl)-1,3,5-triazine monohydrate. Acta Crystallographica. Section E: Structure Reports Online, 61(6), O1900-O1901.
  • Amoore, J., Kepert, C. (2005). 4-(4-pyridylamino)pyridinium isophthalate. Acta Crystallographica. Section E: Structure Reports Online, 61, O3937-O3938.
  • Halder, G., Neville, S., Kepert, C. (2005). A highly distorted (10,3)-a coordination framework constructed from alternating T-shaped and trigonal nodes. CrystEngComm, 7, 266-268.
  • Halder, G., Kepert, C. (2005). A three-dimensional hydrogen-bonded coordination framework: catena-poly[[[tetraaquairon(II)]-mu-4,4 '-bipyridine] benzene-1,4-dicarboxylate]. Acta Crystallographica. Section E: Structure Reports Online, 61, M113-M114.
  • Chapman, K., Chupas, P., Kepert, C. (2005). Direct observation of a transverse vibrational mechanism for negative thermal expansion in Zn(CN)2: An atomic pair distribution function analysis. Journal of the American Chemical Society, 127(44), 15630-15636.
  • Goodwin, A., Chapman, K., Kepert, C. (2005). Guest-dependent negative thermal expansion in nanoporous Prussian Blue analogues MIIPtIV(CN)6 · x{H 2O} (0 [less-than or equal to] X [less-than or equal to] 2; M = Zn, Cd). Journal of the American Chemical Society, 127(51), 17980-17981.
  • Halder, G., Kepert, C. (2005). In situ single-crystal X-ray diffraction studies of desorption and sorption in a flexible nanoporous molecular framework material. Journal of the American Chemical Society, 127(21), 7891-7900.
  • Halder, G., Kepert, C. (2005). Iron(II) molecular framework materials with 4,4 '-azopyridine. Australian Journal of Chemistry: an international journal for chemical science, 58(5), 311-314.
  • Goodwin, A., Kepert, C. (2005). Negative thermal expansion and low-frequency modes in cyanide-bridged framework materials. Physical Review B (Condensed Matter and Materials Physics), 71(14), 140301-1-140301-4.
  • Mulyana, Y., Kepert, C., Lindoy, L., McMurtrie, J. (2005). New cadmium(II) and iron(II) coordination frameworks incorporating a di(4-pyridyl)isoindoline ligand. European Journal of Inorganic Chemistry, 2005 (12), 2470-2475. [More Information]
  • Mulyana, Y., Kepert, C., Lindoy, L., Parkin, A., Turner, P. (2005). New cobalt(II) and zinc(II) coordination frameworks incorporating a pyridyl-pyrazole ditopic ligand. Dalton Transactions: an international journal of inorganic, organometallic and bioinorganic chemistry, 2005 (9), 1598-1601.
  • Kurmoo, M., Kumagai, H., Chapman, K., Kepert, C. (2005). Reversible ferromagnetic-antiferromagnetic transformation upon dehydration-hydration of the nanoporous coordination framework, [Co-3(OH)(2)(C4O4)(2)]center dot 3H(2)O. Chemical Communications, 2005 (24), 3012-3014.
  • Chapman, K., Southon, P., Weeks, C., Kepert, C. (2005). Reversible hydrogen gas uptake in nanoporous Prussian Blue analogues. Chemical Communications, 2005 (26), 3322-3324.
  • Chapman, K., Chupas, P., Kepert, C. (2005). Selective recovery of dynamic guest structure, in a nanoporous Prussian blue through in situ X-ray diffraction: A differential pair distribution function analysis. Journal of the American Chemical Society, 127(32), 11232-11233.
  • Rujiwatra, A., Mander, G., Kepert, C., Rosseinsky, M. (2005). Synthesis and characterization of subcell-supercell related ethylenediamine-pillared zinc hydroxysulfates. Crystal Growth and Design, 5(1), 183-189.

2004

  • Murray, K., Kepert, C. (2004). Cooperativity In Spin Crossover Systems: Memory, Magnetism And Microporosity. In Philipp Gutlich & Harold A. Goodwin (Eds.), Topics in Current Chemistry: Volume 233 - Spin Crossover in Transition Metal Compounds I, (pp. 195-228). Berlin: Springer.
  • Ganesan, P., Kepert, C. (2004). Nanoporosity Of An Interpenetrated Nbo-Type Molecular Framework Studied By Single Crystal X-Ray Diffraction. Chemical Communications, (19), 2168-2169.

2003

  • Kumagai, H., Chapman, K., Kepert, C., Kurmoo, M. (2003). Binary metal(II) - pyromellitate coordinates polymers, M2(pm) (M=Co, Fe, Mn): synthesis, structures and magnetic properties. Polyhedron, 22(14-17), 1921-1927.
  • Kurmoo, M., Kumagai, H., Neville, S., Kepert, C. (2003). Reversible guest exchange and ferrimagnetism (Tc = 60.5 K) in a porous cobalt(II)-hydroxide layer structure pillared with trans-1,4-cyclohexanedicarboxylate. Inorganic Chemistry, 42(21), 6709-6722.

2002

  • Kumagai, H., Kepert, C., Kurmoo, M. (2002). Construction of Hydrogen-Bonded and Coordination-Bonded Networks of Cobalt(II) with Pyromellitate: Synthesis, Structures, and Magnetic Properties. Inorganic Chemistry, 41(13), 3410-3422.
  • Cussen, E., Claridge, J., Rosseinsky, M., Kepert, C. (2002). Flexible Sorption and Transformation Behavior in a Microporous Metal-Organic Framework. Journal of the American Chemical Society, 124(32), 9574-9581.
  • Halder, G., Kepert, C., Moubaraki, B., Murray, K., Cashion, J. (2002). Guest-Dependent Spin Crossover in a Nanoporous Molecular Framework Material. Science, 298(29 Nov), 1762-1765.

2001

  • Kepert, C., Fletcher, A., Cussen, E., Prior, N., Rosseinsky, M., Thomas, K. (2001). Adsorption dynamics of gases and vapors on the nanoporous metal organic framework material Ni2(4,4'-bipyridine)3(NO3)4: Guest modification of host sorption behavior. Journal of the American Chemical Society, 123, 10001-10011.
  • Kepert, C., Rujiwatra, A., Claridge, J., Rosseinsky, M., Kumagai, H., Kurmoo, M. (2001). Layered cobalt hydroxysulfates with both rigid and flexible organic pillars: Synthesis, structure, porosity, and cooperative magnetism. Journal of the American Chemical Society, 123, 10584-10594.
  • Kepert, C., Figgis, B., Sobolev, A., Kurmoo, M. (2001). MEM(TCNQ)2 at room temperature and 10 K, and the absence of a spin-Peierls transition. Acta Crystallographica. Section C: Crystal Structure Communications, C57, 991-993.
  • Kepert, C., Jestadt, T., Kurmoo, M., Blundell,, S., Pratt, F., Husmann,, A., Prassides, K., Lovett,, B., Marshall, I., et, A. (2001). Muon-spin-rotation and magnetization study of metal-organic magnets based on the dicyanamide anion. Journal of Physics: Condensed Matter, 13, 2263-2270.

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