Outline

Overview

Coordination compounds, with bonds between a central metal atom and surrounding ligands, play critical roles in biology, biochemistry and medicine, controlling the structure and function of many enzymes and their metabolism. They play similarly vital roles in many industrial processes and in the development of new materials with specifically designed properties. Building on the foundation of crystal field theory, this course offers a comprehensive treatment of the structures and properties of coordination compounds, with a qualitative molecular orbital description of metal-ligand bonds, and their spectroscopic, magnetic and dynamic effects. The exploitation of these properties in medicine and materials will be emphasized. Medical topics include descriptions of the essential and toxic elements of the Periodic Table, metal complexes as anti-bacterial, anti-inflammatory and anti-cancer drugs, and their use as tumour imaging and radiotherapeutic agents. Materials topics include metal directed self assembly into unique structures, ligand design and control of the synthesis of nanoporous materials with new electronic and magnetic properties and applications in catalysis and molecular separations.

Unit details and rules

Academic unit	Chemistry Academic Operations
Credit points	6
Prerequisites ?	[(CHEM2401 or CHEM2911 or CHEM2915) AND (CHEM2402 or CHEM2912 or CHEM2916)] OR (CHEM2521 or CHEM2921 or CHEM2991)
Corequisites ?	None
Prohibitions ?	CHEM3914
Assumed knowledge ?	None
Available to study abroad and exchange students	Yes

Teaching staff

Coordinator	Girish Lakhwani, girish.lakhwani@sydney.edu.au
Lecturer(s)	Ronald Clarke, ronald.clarke@sydney.edu.au

Type	Description	Weight	Due	Length
Final exam (Record+)	Examination Canvas examination made up of short answer questions.	48%	Formal exam period	2 hours
Outcomes assessed:
Assignment	Investigative lab report and presentation Lab report submitted on Canvas and Presentation done online.	40%	Multiple weeks	See canvas for details
Outcomes assessed:
Assignment	Written assignment 1 See canvas for details	6%	Week 09	See canvas for details
Outcomes assessed:
Assignment	Written assignment 2 See canvas for details	6%	Week 12	See canvas for details
Outcomes assessed:
= hurdle task ? = Type B final exam ?

Assessment summary

Theory: The theory course represents 60% of the unit mark. You must pass the theory component to pass the unit. Theory assessment comprise of final examination and written assignments. Final examination covers the whole of the lecture course and is made up of short answer questions. Past exam papers are available on the Canvas site for this unit.
Laboratory: The laboratory course represents 40% of the unit mark. It is assessed through a variety of in-class and online activities. You must pass the laboratory component to pass the unit. In addition, you must attend 90% of allocated experimental sessions to pass the laboratory course.

NOTE: Due to the current circumstances, we are offering students with a reduced number of lab exercises.

Assessment criteria

The University awards common result grades, set out in the Coursework Policy 2014 (Schedule 1).

As a general guide, a high distinction indicates work of an exceptional standard, a distinction a very high standard, a credit a good standard, and a pass an acceptable standard.

Result name	Mark range	Description
High distinction	85 - 100	At HD level, a student demonstrates a flair for the subject as well as a detailed and comprehensive understanding of the unit material. A ‘High Distinction’ reflects exceptional achievement and is awarded to a student who demonstrates the ability to apply their subject knowledge and understanding to produce original solutions for novel or highly complex problems and/or comprehensive critical discussions of theoretical concepts.
Distinction	75 - 84	At DI level, a student demonstrates an aptitude for the subject and a well-developed understanding of the unit material. A ‘Distinction’ reflects excellent achievement and is awarded to a student who demonstrates an ability to apply their subject knowledge and understanding of the subject to produce good solutions for challenging problems and/or a reasonably well-developed critical analysis of theoretical concepts.
Credit	65 - 74	At CR level, a student demonstrates a good command and knowledge of the unit material. A ‘Credit’ reflects solid achievement and is awarded to a student who has a broad general understanding of the unit material and can solve routine problems and/or identify and superficially discuss theoretical concepts.
Pass	50 - 64	At PS level a student demonstrates proficiency in the unit material. A ‘Pass’ reflects satisfactory achievement and is awarded to a student who has threshold knowledge.
Fail	0 - 49	When you don’t meet the learning outcomes of the unit to a satisfactory standard.

For more information see guide to grades.

Late submission

In accordance with University policy, these penalties apply when written work is submitted after 11:59pm on the due date:

Deduction of 5% of the maximum mark for each calendar day after the due date.
After ten calendar days late, a mark of zero will be awarded.

Academic integrity

The Current Student website provides information on academic integrity and the resources available to all students. The University expects students and staff to act ethically and honestly and will treat all allegations of academic integrity breaches seriously.

We use similarity detection software to detect potential instances of plagiarism or other forms of academic integrity breach. If such matches indicate evidence of plagiarism or other forms of academic integrity breaches, your teacher is required to report your work for further investigation.

Use of generative artificial intelligence (AI) and automated writing tools

You may only use generative AI and automated writing tools in assessment tasks if you are permitted to by your unit coordinator. If you do use these tools, you must acknowledge this in your work, either in a footnote or an acknowledgement section. The assessment instructions or unit outline will give guidance of the types of tools that are permitted and how the tools should be used.

Your final submitted work must be your own, original work. You must acknowledge any use of generative AI tools that have been used in the assessment, and any material that forms part of your submission must be appropriately referenced. For guidance on how to acknowledge the use of AI, please refer to the AI in Education Canvas site.

The unapproved use of these tools or unacknowledged use will be considered a breach of the Academic Integrity Policy and penalties may apply.

Studiosity is permitted unless otherwise indicated by the unit coordinator. The use of this service must be acknowledged in your submission as detailed on the Learning Hub’s Canvas page.

Outside assessment tasks, generative AI tools may be used to support your learning. The AI in Education Canvas site contains a number of productive ways that students are using AI to improve their learning.

Learning support

Simple extensions

If you encounter a problem submitting your work on time, you may be able to apply for an extension of five calendar days through a simple extension.  The application process will be different depending on the type of assessment and extensions cannot be granted for some assessment types like exams.

Special consideration

If exceptional circumstances mean you can’t complete an assessment, you need consideration for a longer period of time, or if you have essential commitments which impact your performance in an assessment, you may be eligible for special consideration or special arrangements.

Special consideration applications will not be affected by a simple extension application.

Using AI responsibly

Co-created with students, AI in Education includes lots of helpful examples of how students use generative AI tools to support their learning. It explains how generative AI works, the different tools available and how to use them responsibly and productively.

Weekly schedule

WK	Topic	Learning activity
Multiple weeks	Electronic structure and spectroscopy of d-block complexes, Lanthanoids and actinoids, Discrete metallosupramolecular chemistry, Supramolecular materials	Lecture (10 hr)
	Metal complex reactivity, Electron transfer reactions	Lecture (6 hr)
	Essential & toxic metals, Toxic metals & metal-based therapeutics, Metal-based therapeutics, Metal-based imaging	Lecture (8 hr)
	lab exercises	Practical (40 hr)

Attendance and class requirements

Attendance: All students are expected to attend all lectures, practial classes and tutorials. A variety of notes, handouts, data sheets, and information provided throughout the Unit of Study are intended to supplement the lectures not to substitute for them. Absences from any scheduled pratical sessions and tutorials must be explained and supported by appropriate documentation. Even if special consideration has been granted, it is the student's responsibility to know and understand the material covered in the missed sessions. Please note that the Faculty of Science has a miniumum 80% attendance requirement for a student to pass any unit of study (see Faculty of Science Resolutions at http://sydney.edu.au/handbooks/science/rules/faculty_resolutions.shtml).

Study commitment

Typically, there is a minimum expectation of 1.5-2 hours of student effort per week per credit point for units of study offered over a full semester. For a 6 credit point unit, this equates to roughly 120-150 hours of student effort in total.

Learning outcomes

Learning outcomes are what students know, understand and are able to do on completion of a unit of study. They are aligned with the University's graduate qualities and are assessed as part of the curriculum.

Outcomes
Graduate qualities

At the completion of this unit, you should be able to:

LO1. demonstrate an understanding of the concepts including crystal field theory and its application in the treatment of structure-function relationships of coordination compounds.
LO2. explain and predict how spectroscopic, magnetic and dynamic properties of metal complexes can be exploited in medicine and materials science.
LO3. demonstrate the ability to perform safe laboratory manipulations and to handle glassware
LO4. demonstrate the ability to find and analyse information and judge its reliability and significance
LO5. demonstrate the ability to communicate scientific information appropriately both orally and through written work
LO6. demonstrate the ability to engage in team and group work for scientific investigations and for the process of learning
LO7. demonstrate a sense of responsibility and independence as a learner and as a scientist
LO8. demonstrate basic skills in computing, numeracy and data handling.

Graduate qualities

The graduate qualities are the qualities and skills that all University of Sydney graduates must demonstrate on successful completion of an award course. As a future Sydney graduate, the set of qualities have been designed to equip you for the contemporary world.

GQ1	Depth of disciplinary expertise Deep disciplinary expertise is the ability to integrate and rigorously apply knowledge, understanding and skills of a recognised discipline defined by scholarly activity, as well as familiarity with evolving practice of the discipline.
GQ2	Critical thinking and problem solving Critical thinking and problem solving are the questioning of ideas, evidence and assumptions in order to propose and evaluate hypotheses or alternative arguments before formulating a conclusion or a solution to an identified problem.
GQ3	Oral and written communication Effective communication, in both oral and written form, is the clear exchange of meaning in a manner that is appropriate to audience and context.
GQ4	Information and digital literacy Information and digital literacy is the ability to locate, interpret, evaluate, manage, adapt, integrate, create and convey information using appropriate resources, tools and strategies.
GQ5	Inventiveness Generating novel ideas and solutions.
GQ6	Cultural competence Cultural Competence is the ability to actively, ethically, respectfully, and successfully engage across and between cultures. In the Australian context, this includes and celebrates Aboriginal and Torres Strait Islander cultures, knowledge systems, and a mature understanding of contemporary issues.
GQ7	Interdisciplinary effectiveness Interdisciplinary effectiveness is the integration and synthesis of multiple viewpoints and practices, working effectively across disciplinary boundaries.
GQ8	Integrated professional, ethical, and personal identity An integrated professional, ethical and personal identity is understanding the interaction between one’s personal and professional selves in an ethical context.
GQ9	Influence Engaging others in a process, idea or vision.

Outcome map

Learning outcomes	Graduate qualities
Learning outcomes

Responding to student feedback

This section outlines changes made to this unit following staff and student reviews.

No changes have been made since this unit was last offered

Additional information

Disclaimer

The University reserves the right to amend units of study or no longer offer certain units, including where there are low enrolment numbers.

To help you understand common terms that we use at the University, we offer an online glossary.

Current students

Overview

Overview

Unit details and rules

Teaching staff

Assessment

Assessment

Assessment summary

Assessment criteria

Late submission

Academic integrity

Learning support

Learning support

Simple extensions

Special consideration

Using AI responsibly

Weekly schedule

Weekly schedule

Attendance and class requirements

Study commitment

Learning outcomes

Learning outcomes

Graduate qualities

Outcome map

Responding to student feedback

Responding to student feedback

Additional information

Additional information

Disclaimer

On this page

Useful links

Media

Student links

About us

Connect

Current students

CHEM3114: Metal Complexes: Medicine and Materials

Semester 2, 2020 [Normal day] - Camperdown/Darlington, Sydney

Overview

Overview

Unit details and rules

Teaching staff

Assessment

Assessment

Assessment summary

Assessment criteria

Late submission

Academic integrity

Learning support

Learning support

Simple extensions

Special consideration

Using AI responsibly

Weekly schedule

Weekly schedule

Attendance and class requirements

Study commitment

Learning outcomes

Learning outcomes

Graduate qualities

Outcome map

Responding to student feedback

Responding to student feedback

Additional information

Additional information

Disclaimer

On this page

Useful links

Media

Student links

About us

Connect